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- W4239371707 abstract "Publisher SummarySilicon dioxide (SiO2) has many polymorphs developed through different pressure, temperature, and chemical environments. The stability fields and crystal chemical properties at high temperature and pressure of the SiO2 polymorphs melts and glasses have been extensively studied. These phases represent archetypal framework structures, which provide insights into the intrinsic behavior of the Si–O linkages. Under AB2 structure, the quartz form of SiO2 is a very important piezoelectric material used for transducers and frequency-control devices. Large crystals of quartz are grown commercially in large pressure vessels from the system, Na2O–SiO2–H2O, at about 1 kbar and 500˚C. A view of the structure of α-SiO2 called “quartz” is shown in the chapter. The formation of probably disordered, metastable crystalline phases during room-temperature compression seems to be a general feature on the pathway to pressure-induced amorphization for most of the known SiO2 polymorphs. The chapter shows the way in situ Raman spectroscopy reveals the passage of crystalline α-phase to another crystalline polymorph and finally to an amorphous phase characterized by a strong decrease in Raman intensity and the growth of broad, glassy bands similar to those observed in silica glass compressed to the same pressure." @default.
- W4239371707 created "2022-05-12" @default.
- W4239371707 date "2004-01-01" @default.
- W4239371707 modified "2023-09-26" @default.
- W4239371707 title "Chapter 12 Simple oxides and carbonates" @default.
- W4239371707 doi "https://doi.org/10.1016/s0921-3198(04)80014-0" @default.
- W4239371707 hasPublicationYear "2004" @default.
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