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- W4239453602 abstract "The first, oxidative photocatalytic method for phenol-phenol homo-coupling and cross-coupling is described and isolated yields of up to 97% are obtained. Measured oxidation potentials and computed nucleophilicity parameters are consistent with a nucleophilic attack of one partner onto the oxidized radical form of the other partner. Understanding of this model permitted development of cross-coupling reactions between nucleophilic phenols/arenes and easily oxidized phenols in high selectivity and efficiency. A highlight of this method is that one equivalent of each coupling partner is utilized. Building on these findings, the first non-enzymatic, catalytic method for coupling tyrosine was developed." @default.
- W4239453602 created "2022-05-12" @default.
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- W4239453602 date "2020-02-18" @default.
- W4239453602 modified "2023-09-26" @default.
- W4239453602 title "Oxidative Photocatalytic Homo- and Cross-Coupling of Phenols: Non-Enzymatic, Catalytic Method for Coupling Tyrosine" @default.
- W4239453602 doi "https://doi.org/10.26434/chemrxiv.11813403.v1" @default.
- W4239453602 hasPublicationYear "2020" @default.
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