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- W4239551755 abstract "A cobalt complex with nitronyl nitroxide, Co(hfac)2(NITPh-p-Br)2 (hfac = hexafluoroacetylacetonate; NITPh-p-Br = 2-(4/-bromophenyl)-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) was synthesized. The complex has been investigated by X-ray crystal diffraction and magnetic susceptibility measurements. The crystal structure consists of Radical-Co-Radical tri-spin units, in which the central Co(II) ion is coordinated by four oxygen atoms from two hfac and two oxygen atoms from the NITPh-p-Br. Furthermore, dimmer structure [Co(hfac)2(NITPh-p-Br)2]2 is formed through hydrogen bond interaction between the hydrogen atom of C-H group from hfac ligand and the fluorine atom of C-F group from another hafc ligand. Magnetic susceptibility measurements indicate that the Co(II) ions interact antiferromagnetically with the directly bonding nitroxide group of the radicals." @default.
- W4239551755 created "2022-05-12" @default.
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- W4239551755 date "2012-12-28" @default.
- W4239551755 modified "2023-10-16" @default.
- W4239551755 title "Synthesis, Crystal Structures, and Magnetic Properties of a Cobalt Complex with Nitronyl Nitroxide Radical" @default.
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- W4239551755 doi "https://doi.org/10.1080/15533174.2012.680093" @default.
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