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- W4239604868 abstract "The kinetics were determined for the polymerization of butadiene, isoprene, and styrene with n-, sec-, and tert-BuLi in hydrocarbon solvents. Polymerization has the mechanism of a homogeneous, “intermittent” stepwise addition reaction with no true termination reaction. In cyclohexane, n-hexane or toluene at 5–50°C. there is no chain transfer. When n-BuLi was used, the rate of polymerization was a combined rate of initiation and propagation. It was proportional to [M]2 and dependent on [n-BuLi] at low initiator concentration and almost independent at high concentration. The limits are established and discussed. The rate constants calculated for the monomers were in the order styrene > isoprene ≫ butadiene. For the solvents the order was toluene ≫ cyclohexane > n-hexane." @default.
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- W4239604868 date "1965-01-01" @default.
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- W4239604868 title "Kinetics of polymerization of butadiene, isoprene, and styrene with alkyllithiums. Part I. Rate of polymerization" @default.
- W4239604868 doi "https://doi.org/10.1002/pol.1965.100030117" @default.
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