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- W4239623770 abstract "Infrared spectra of polycrystalline K 2 HgCl 4 .H 2 O at different degrees of deuteration were recorded, in the 4000–250 cm −1 region, at temperatures between liquid-nitrogen and 130 °C. The spectra confirm the existence of a single type of water molecule, engaged in two equivalent hydrogen bonds. The value of 2548 cm −1 for the isolated O—D stretching frequency leads to an estimate of 3.25(3) Å for the O … Cl hydrogen-bond distance, in excellent agreement with the results of X-ray and neutron diffraction. Dynamic coupling is appreciable for stretch, bend, and librational fundamentals but is weaker than in CuCl 2 .2H 2 O or K 2 CuCl 4 .2H 2 O, in which the water molecules in the crystal are more tightly bonded.A number of corrected values are reported of isolated O—D stretching frequencies in hydrates studied previously." @default.
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- W4239623770 date "1977-05-15" @default.
- W4239623770 modified "2023-09-25" @default.
- W4239623770 title "Infrared studies of water in crystalline hydrates: K<sub>2</sub>HgCl<sub>4</sub>.H<sub>2</sub>O" @default.
- W4239623770 doi "https://doi.org/10.1139/v77-245" @default.
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