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- W4239650006 abstract "The isomerisation of glucose to fructose is a critical step towards manufacturing petroleum-free chemicals from lignocellulosic biomass. Herein we show that Hf-containing zeolites are unique catalysts for this reaction, enabling true thermodynamic equilibrium to be achieved in a single step during intensified continuous operation, which no chemical or biological catalyst has yet been able to achieve. Unprecedented single-pass yields of 58 % are observed at a fructose selectivity of 94 %, and continuous operation for over 100 hours is demonstrated. The unexpected performance of the catalyst is realised following a period of activation within the reactor, during which time interaction with the solvent generates a state of activity that is absent in the synthesised catalyst. Mechanistic studies by X-ray absorption spectroscopy, chemisorption FTIR, operando UV/Vis and 1H–13C HSQC NMR spectroscopy indicate that activity arises from isolated HfIV atoms with monofunctional acidic properties." @default.
- W4239650006 created "2022-05-12" @default.
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- W4239650006 date "2020-08-31" @default.
- W4239650006 modified "2023-10-17" @default.
- W4239650006 title "Solvent‐Activated Hafnium‐Containing Zeolites Enable Selective and Continuous Glucose–Fructose Isomerisation" @default.
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- W4239650006 doi "https://doi.org/10.1002/ange.202006718" @default.
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