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- W4239696528 abstract "Unumkehrbar: Die zentrale Rolle von Lewis-Base-Promotoren L in der Pauson-Khand-Reaktion wurde mithilfe von DFT-Rechnungen untersucht. Anders als derzeit angenommen, beschleunigen die Promotoren nicht die Abspaltung eines zweiten CO-Liganden vom Acetylendicobalt-Komplex, um Platz für die Olefinkoordination zu schaffen, sondern sie stabilisieren das Olefininsertionsprodukt (siehe Schema), womit die Produktbildung im Wesentlichen irreversibel ist." @default.
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- W4239696528 date "2005-09-01" @default.
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- W4239696528 title "Lewis Base Promoters in the Pauson-Khand Reaction: A Different Scenario" @default.
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- W4239696528 doi "https://doi.org/10.1002/ange.200500955" @default.
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