Matches in SemOpenAlex for { <https://semopenalex.org/work/W4239779733> ?p ?o ?g. }
- W4239779733 abstract "(NiCl2) [7718-54-9] Cl2Ni (MW 129.59) InChI = 1S/2ClH.Ni/h2*1H;/q;;+2/p-2 InChIKey = QMMRZOWCJAIUJA-UHFFFAOYSA-L (NiCl2ċ6H2O) [7791-20-0] Cl2H12NiO6 (MW 237.71) InChI = 1S/2ClH.Ni.6H2O/h2*1H;;6*1H2/q;;+2;;;;;;/p-2 InChIKey = LAIZPRYFQUWUBN-UHFFFAOYSA-L (mild Lewis acid;2-5 catalyst for coupling reactions,1a,7-12 and in combination with complex hydrides as a selective reducing agent16, 33, 36-38) Physical Data: mp 1001 °C; d 3.550 g cm−3. Solubility: sol H2O, alcohol; insol most organic solvents. Form Supplied in: yellow solid when anhydrous, green solid for the hydrate; widely available. Drying: for anhydrous nickel chloride, standard procedure for drying metal chlorides can be used by refluxing with Thionyl Chloride followed by removal of excess SOCl2.45 Handling, Storage, and Precautions: nickel(II) is reputed to be toxic and a cancer suspect agent. Use in a fume hood." @default.
- W4239779733 created "2022-05-12" @default.
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- W4239779733 date "2001-04-15" @default.
- W4239779733 modified "2023-10-18" @default.
- W4239779733 title "Nickel(II) Chloride" @default.
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- W4239779733 doi "https://doi.org/10.1002/047084289x.rn012" @default.
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