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- W4239798522 abstract "The kinetics of the cis—trans photoisomerization of 1-phenylcyclohexene via the triplet state, studied by either nanosecond pulse radiolysis or laser flash photolysis in the presence of sensitizers, reveal that the triplet species involved in the isomerization mechanism has a lifetime of 55 ns in fluid solution at room temperature. A transient absorption decaying with the same 55 ns lifetime, and therefore assigned to this triplet species, was observed in the 320 – 345 nm region. Quite similar triplet—triplet absorptions were observed with 1-phenylcycloheptene, 1-phenylpropene and styrene itself. From the experimental results and from considerations of the energy surfaces of the excited states of styrene, the observed triplet species is identified as the perpendicular (or “phantom”) triplet state of the styrene moiety." @default.
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- W4239798522 date "1979-06-01" @default.
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- W4239798522 title "Cis—trans isomerization of styrenes via the triplet pathway: the perpendicular triplet state observed by laser flash photolysis" @default.
- W4239798522 doi "https://doi.org/10.1016/0047-2670(79)80051-9" @default.
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