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- W4239985670 abstract "Kontrollierte Fusion: Mit einer seco-Ring-D-Vorstufe für die Kontrolle der Stereochemie der entscheidenden Cycloaddition mit Acetaldehyd und der Richtung der Protonierung des resultierenden Silylenolethercycloaddukts gelang die Totalsynthese von Grandisin A, das eine vielversprechende Selektivität für die Bindung an den δ-Opioidrezeptor zeigt. Der Ring D wird zum Schluss aufgebaut (siehe Schema, LA=Lewis-Säure). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2001/2007/z703245_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W4239985670 date "2007-10-15" @default.
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- W4239985670 title "Conformational Locking through Allylic Strain as a Device for Stereocontrol—Total Synthesis of Grandisine A" @default.
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