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Matches in SemOpenAlex for { <https://semopenalex.org/work/W4240026805> ?p ?o ?g. }

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• W4240026805 abstract "The efficient RhI-catalyzed cycloisomerization of benzylallene-alkynes produced the tricyclo[9.4.0.03,8]pentadecapentaene skeleton through a CH bond activation in good yields. A plausible reaction mechanism proceeds via oxidative addition of the acetylenic CH bond to RhI, an ene-type cyclization to the vinylidenecarbene–RhI intermediate, and an electrophilic aromatic substitution with the vinylidenecarbene species. It was proposed based on deuteration and competition experiments." @default.
• W4240026805 created "2022-05-12" @default.
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• W4240026805 date "2014-05-30" @default.
• W4240026805 modified "2023-09-30" @default.
• W4240026805 title "Rhodium(I)-Catalyzed Cycloisomerization of Benzylallene-Alkynes through CH Activation" @default.
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• W4240026805 doi "https://doi.org/10.1002/ange.201403990" @default.
• W4240026805 hasPublicationYear "2014" @default.
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