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- W4240071657 abstract "The effect of the boric acid concentration on the color reaction between partially saponified poly(vinyl acetate), which is dissolvable in water, and iodine-iodide was investigated. As the concentration of boric acid increased, the absorbance at λmax = 488 nm of the red-violet complex, which is due to a long sequence of vinyl acetate units distributed along the polymer chain, increased gradually, reached a maximum, and then decreased from the point in which the absorbance at λmax = 656nm of the blue complex, based on the vinyl alcohol units in the polymer, was observed. The color complex in an excess of boric acid transferred from red-violet to red-tinged blue with time. From the color change, the molar absorption coefficient at λmax = 656 nm for the iodine molecule in the blue complex was found to be 3,92.104l/(mol cm)." @default.
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- W4240071657 date "1977-06-01" @default.
- W4240071657 modified "2023-10-17" @default.
- W4240071657 doi "https://doi.org/10.1002/macp.1977.021780608" @default.
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