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- W4240095140 endingPage "9219" @default.
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- W4240095140 abstract "Abstract Methods for the highly stereoselective and regiodivergent hydrosilylation of 1,3‐disubstituted allenes have been developed. The synthesis of E allylsilanes is accomplished with palladium NHC catalysts, and trisubstituted Z alkenylsilanes are accessed with nickel NHC catalysts. Unsymmetrically substituted allenes are well tolerated with nickel catalysis and afford Z alkenylsilanes. Evidence for a plausible mechanism was obtained through an isotopic double‐labeling crossover study." @default.
- W4240095140 created "2022-05-12" @default.
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- W4240095140 date "2015-06-16" @default.
- W4240095140 modified "2023-10-18" @default.
- W4240095140 title "Regiodivergent and Stereoselective Hydrosilylation of 1,3-Disubstituted Allenes" @default.
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- W4240095140 doi "https://doi.org/10.1002/ange.201503521" @default.
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