Matches in SemOpenAlex for { <https://semopenalex.org/work/W4240136355> ?p ?o ?g. }
- W4240136355 endingPage "11047" @default.
- W4240136355 startingPage "11044" @default.
- W4240136355 abstract "Abstract A general and efficient rhodium‐catalyzed asymmetric cyanide‐free hydrocyanation of alkenes has been developed. Based on the asymmetric hydroformylation/condensation/aza‐Cope elimination sequences, a broad scope of substrates including mono‐substituted, 1,2‐, and 1,1‐disubstituted alkenes (involving natural product R ‐ and S ‐limonene) were employed, and a series of valuable chiral nitriles are prepared with high yields (up to 95 %) and enantioselectivities (up to 98 % ee ). Notably, the critical factor to achieve high enantioseletivies is the addition of catalytic amount of benzoic acid. This novel methodology provides an efficient and concise synthetic route to the intermediate of vildagliptin and anagliptin." @default.
- W4240136355 created "2022-05-12" @default.
- W4240136355 creator A5006955033 @default.
- W4240136355 creator A5014406366 @default.
- W4240136355 creator A5020870214 @default.
- W4240136355 creator A5032905435 @default.
- W4240136355 creator A5059867062 @default.
- W4240136355 creator A5066656843 @default.
- W4240136355 creator A5083633473 @default.
- W4240136355 date "2019-07-09" @default.
- W4240136355 modified "2023-10-14" @default.
- W4240136355 title "Asymmetric Hydrocyanation of Alkenes without HCN" @default.
- W4240136355 cites W1967932228 @default.
- W4240136355 cites W1988946448 @default.
- W4240136355 cites W1992272109 @default.
- W4240136355 cites W1993287695 @default.
- W4240136355 cites W1998890001 @default.
- W4240136355 cites W2002592801 @default.
- W4240136355 cites W2048685361 @default.
- W4240136355 cites W2062272389 @default.
- W4240136355 cites W2063274092 @default.
- W4240136355 cites W2066778685 @default.
- W4240136355 cites W2067338689 @default.
- W4240136355 cites W2079850929 @default.
- W4240136355 cites W2080325613 @default.
- W4240136355 cites W2084781784 @default.
- W4240136355 cites W2103617763 @default.
- W4240136355 cites W2111217208 @default.
- W4240136355 cites W2120397384 @default.
- W4240136355 cites W2122431687 @default.
- W4240136355 cites W2143975870 @default.
- W4240136355 cites W2156906633 @default.
- W4240136355 cites W2161214956 @default.
- W4240136355 cites W2164410506 @default.
- W4240136355 cites W2233195912 @default.
- W4240136355 cites W2320356206 @default.
- W4240136355 cites W2462779433 @default.
- W4240136355 cites W2472267435 @default.
- W4240136355 cites W2515068481 @default.
- W4240136355 cites W2580403504 @default.
- W4240136355 cites W2734492052 @default.
- W4240136355 cites W2765308013 @default.
- W4240136355 cites W2789967616 @default.
- W4240136355 cites W2791724783 @default.
- W4240136355 cites W2795937930 @default.
- W4240136355 cites W2887501016 @default.
- W4240136355 cites W2891611419 @default.
- W4240136355 cites W2949181117 @default.
- W4240136355 cites W2951136451 @default.
- W4240136355 cites W2951831833 @default.
- W4240136355 cites W2952019070 @default.
- W4240136355 cites W2952894433 @default.
- W4240136355 cites W3004855455 @default.
- W4240136355 cites W3146528461 @default.
- W4240136355 cites W4211046907 @default.
- W4240136355 cites W4229730533 @default.
- W4240136355 cites W4232762620 @default.
- W4240136355 cites W4237915111 @default.
- W4240136355 cites W4238603086 @default.
- W4240136355 cites W4240131849 @default.
- W4240136355 cites W4244517121 @default.
- W4240136355 cites W4376477696 @default.
- W4240136355 cites W962028432 @default.
- W4240136355 doi "https://doi.org/10.1002/ange.201906111" @default.
- W4240136355 hasPublicationYear "2019" @default.
- W4240136355 type Work @default.
- W4240136355 citedByCount "6" @default.
- W4240136355 countsByYear W42401363552020 @default.
- W4240136355 countsByYear W42401363552022 @default.
- W4240136355 countsByYear W42401363552023 @default.
- W4240136355 crossrefType "journal-article" @default.
- W4240136355 hasAuthorship W4240136355A5006955033 @default.
- W4240136355 hasAuthorship W4240136355A5014406366 @default.
- W4240136355 hasAuthorship W4240136355A5020870214 @default.
- W4240136355 hasAuthorship W4240136355A5032905435 @default.
- W4240136355 hasAuthorship W4240136355A5059867062 @default.
- W4240136355 hasAuthorship W4240136355A5066656843 @default.
- W4240136355 hasAuthorship W4240136355A5083633473 @default.
- W4240136355 hasConcept C100805817 @default.
- W4240136355 hasConcept C121332964 @default.
- W4240136355 hasConcept C144251326 @default.
- W4240136355 hasConcept C146686406 @default.
- W4240136355 hasConcept C161790260 @default.
- W4240136355 hasConcept C178790620 @default.
- W4240136355 hasConcept C185592680 @default.
- W4240136355 hasConcept C200093464 @default.
- W4240136355 hasConcept C21951064 @default.
- W4240136355 hasConcept C2778844314 @default.
- W4240136355 hasConcept C2779240715 @default.
- W4240136355 hasConcept C2779953769 @default.
- W4240136355 hasConcept C521398313 @default.
- W4240136355 hasConcept C97355855 @default.
- W4240136355 hasConceptScore W4240136355C100805817 @default.
- W4240136355 hasConceptScore W4240136355C121332964 @default.
- W4240136355 hasConceptScore W4240136355C144251326 @default.
- W4240136355 hasConceptScore W4240136355C146686406 @default.
- W4240136355 hasConceptScore W4240136355C161790260 @default.
- W4240136355 hasConceptScore W4240136355C178790620 @default.