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- W4240194878 abstract "Abstract A neutral mononuclear Fe III complex [Fe III (H‐5‐Br‐thsa‐Me)(5‐Br‐thsa‐Me)]⋅H 2 O ( 1 ; H 2 ‐5‐Br‐thsa‐Me=5‐bromosalicylaldehyde methylthiosemicarbazone) was prepared that exhibited a three‐step spin‐crossover (SCO) with symmetry breaking and a 14 K hysteresis loop owing to strong cooperativity. Two ordered intermediate states of 1 were observed, 4HS–2LS and 2HS–4LS, which exhibited reentrant phase‐transition behavior. This study provides a new platform for examining multistability in SCO complexes." @default.
- W4240194878 created "2022-05-12" @default.
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- W4240194878 date "2016-03-17" @default.
- W4240194878 modified "2023-10-01" @default.
- W4240194878 title "Direct Observation of Ordered High‐Spin–Low‐Spin Intermediate States of an Iron(III) Three‐Step Spin‐Crossover Complex" @default.
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- W4240194878 doi "https://doi.org/10.1002/ange.201511281" @default.
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