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- W4240229612 abstract "Abstract We report three self‐assembled iron complexes that comprised an anti‐parallel open form (o‐ L anti ), a parallel open form ( o ‐ L syn ), and a closed form (c‐ L ) of diarylethene conformers. Under kinetic control, Fe II 2 (o‐ L anti ) 3 was isolated, which exhibited a dinuclear structure with diamagnetic properties. Under light‐irradiation control, Fe II 2 (c‐ L ) 3 was prepared and exhibited paramagnetism and spin‐crossover behaviour. Under thermodynamic control and in the presence of indispensable [Fe III (Tp*)(CN) 3 ] − , Fe II 2 (o‐ L anti ) 3 and Fe II 2 (c‐ L ) 3 transformed into tetranuclear Fe III 2 Fe II 2 (o‐ L syn ) 2 , which exhibited complete spin‐crossover behaviour at T 1/2 =353 K." @default.
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- W4240229612 date "2019-02-18" @default.
- W4240229612 modified "2023-10-16" @default.
- W4240229612 title "Structure Switching and Modulation of the Magnetic Properties in Diarylethene‐Bridged Metallosupramolecular Compounds by Controlled Coordination‐Driven Self‐Assembly" @default.
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- W4240229612 doi "https://doi.org/10.1002/ange.201900789" @default.
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