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- W4240283485 abstract "Ungewöhnlich robust: Ein bemerkenswert temperaturunabhängiger Katalysator wurde für die Aldol-analoge Reaktion von Iminen (siehe Schema) entwickelt, die sich von ortho-Aminophenolen ableiten. Der Katalysator wird aus zwei Äquivalenten VAPOL und einem Zirconiumtetraalkoxid präpariert. Die asymmetrische Induktion ist besonders hoch, wenn R1 eine Methylgruppe ist: Die Enantiomerenüberschüsse sind dann größer als 98 % ee – bei Raumtemperatur wie auch bei 100°C. TMS=Me3Si." @default.
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- W4240283485 date "2001-06-18" @default.
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- W4240283485 title "Active Site Design in a Chemzyme: Development of a Highly Asymmetric and Remarkably Temperature-Independent Catalyst for the Imino Aldol Reaction" @default.
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- W4240283485 doi "https://doi.org/10.1002/1521-3757(20010618)113:12<2331::aid-ange2331>3.0.co;2-p" @default.
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