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- W4240504611 abstract "Stability constants are measured for complexes of Cd2+, Ni2+, Cu2+ and Co2+ with pyridine-2,6-dicarboxylic acid(PDA) in water, methanol and water-methanol binary solvent systems at 298.15, 308.15 and 318.15 K by conductometric method. The result shows that the stoichiometry of the complexes of PDA with all metals in all binary solvent systems is 1:2 [ML2]. The logKf values of PDA-M2+ complexes in H2O-MeOH binary solvent systems increase with increasing % of MeOH and temperature. The ΔH0 and ΔS0 of the complexation reaction in the different H2O-MeOH binary solvent systems were evaluated by the temperature dependence of the formation constants using a linear least square analysis according to van’t Hoff equation." @default.
- W4240504611 created "2022-05-12" @default.
- W4240504611 creator A5010669021 @default.
- W4240504611 date "2019-06-04" @default.
- W4240504611 modified "2023-10-17" @default.
- W4240504611 title "Thermodynamic studies on metal complexes of Cd2+, Ni2+, Cu2+ AND Co2+ with pyridine-2,6-dicarboxylic acid in water, methanol and water-methanol binary solvent systems at 298.15 , 308.15 and 318.15 K by conductometric method" @default.
- W4240504611 doi "https://doi.org/10.31221/osf.io/59gx2" @default.
- W4240504611 hasPublicationYear "2019" @default.
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