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- W4240534387 abstract "Initial objectives were to obtain novel thermally stable homoleptic metal complexes [MR'n]: (i) d- or f-block metal alkyls, (ii) subvalent diamagnetic main-group element alkuls (carbene analogues), and (iii) paramagnetic alkyls of main-group elements (alkyl-radical analogues). Subsequently, further targets became (iv) compounds with bridging alkyl ligands for d- or f-block metals, and (v) heteroleptic complexes in which a bulky alkyl group [(Me3Si)2CH = R] allowed the incorporation within the metal inner co-ordination sphere of unexpected co-ligands. Compounds discussed included those listed in Table 4. Among the physical methods used were dynamic n. m. r., e. s. r., X-ray diffraction, and calorimetry." @default.
- W4240534387 created "2022-05-12" @default.
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- W4240534387 date "1979-01-01" @default.
- W4240534387 modified "2023-10-16" @default.
- W4240534387 title "UNUSUAL METAL ALKYLS" @default.
- W4240534387 doi "https://doi.org/10.1016/b978-0-08-022035-2.50014-1" @default.
- W4240534387 hasPublicationYear "1979" @default.
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