FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W4240549069> ?p ?o ?g. }

• W4240549069 endingPage "10123" @default.
• W4240549069 startingPage "10118" @default.
• W4240549069 abstract "An efficient two-step synthesis of the first NHC-stabilized disilavinylidene (Z)-(SIdipp)SiSi(Br)Tbb (2; SIdipp=C[N(C6H3-2,6-iPr2)CH2]2, Tbb=C6H2-2,6-[CH(SiMe3)2]2-4-tBu, NHC=N-heterocyclic carbene) is reported. The first step of the procedure involved a 2:1 reaction of SiBr2(SIdipp) with the 1,2-dibromodisilene (E)-Tbb(Br)SiSi(Br)Tbb at 100 °C, which afforded selectively an unprecedented NHC-stabilized bromo(silyl)silylene, namely SiBr(SiBr2Tbb)(SIdipp) (1). Alternatively, compound 1 could be obtained from the 2:1 reaction of SiBr2(SIdipp) with LiTbb at low temperature. 1 was then selectively reduced with C8K to give the NHC-stabilized disilavinylidene 2. Both low-valent silicon compounds were comprehensively characterized by X-ray diffraction analysis, multinuclear NMR spectroscopy, and elemental analyses. Additionally, the electronic structure of 2 was studied by various quantum-chemical methods." @default.
• W4240549069 created "2022-05-12" @default.
• W4240549069 creator A5002180363 @default.
• W4240549069 creator A5018529571 @default.
• W4240549069 creator A5022851843 @default.
• W4240549069 creator A5033746477 @default.
• W4240549069 creator A5091584990 @default.
• W4240549069 date "2015-07-01" @default.
• W4240549069 modified "2023-10-17" @default.
• W4240549069 title "SiSi Double Bonds: Synthesis of an NHC-Stabilized Disilavinylidene" @default.
• W4240549069 cites W1963546571 @default.
• W4240549069 cites W1967266229 @default.
• W4240549069 cites W1970780400 @default.
• W4240549069 cites W1971428915 @default.
• W4240549069 cites W1972274370 @default.
• W4240549069 cites W1982619946 @default.
• W4240549069 cites W1985542788 @default.
• W4240549069 cites W1986394484 @default.
• W4240549069 cites W1996186986 @default.
• W4240549069 cites W1996656315 @default.
• W4240549069 cites W1999820590 @default.
• W4240549069 cites W2000038867 @default.
• W4240549069 cites W2002950020 @default.
• W4240549069 cites W2003046834 @default.
• W4240549069 cites W2004219719 @default.
• W4240549069 cites W2005918561 @default.
• W4240549069 cites W2015978869 @default.
• W4240549069 cites W2023606366 @default.
• W4240549069 cites W2027333070 @default.
• W4240549069 cites W2027815796 @default.
• W4240549069 cites W2029792202 @default.
• W4240549069 cites W2032908030 @default.
• W4240549069 cites W2034774479 @default.
• W4240549069 cites W2035405851 @default.
• W4240549069 cites W2040964756 @default.
• W4240549069 cites W2055053833 @default.
• W4240549069 cites W2064674762 @default.
• W4240549069 cites W2067180589 @default.
• W4240549069 cites W2069890506 @default.
• W4240549069 cites W2071935393 @default.
• W4240549069 cites W2084221553 @default.
• W4240549069 cites W2084470520 @default.
• W4240549069 cites W2086296254 @default.
• W4240549069 cites W2087743583 @default.
• W4240549069 cites W2093630096 @default.
• W4240549069 cites W2100624455 @default.
• W4240549069 cites W2106258062 @default.
• W4240549069 cites W2108433847 @default.
• W4240549069 cites W2109906017 @default.
• W4240549069 cites W2110298104 @default.
• W4240549069 cites W2110502363 @default.
• W4240549069 cites W2111828476 @default.
• W4240549069 cites W2122375910 @default.
• W4240549069 cites W2126396516 @default.
• W4240549069 cites W2145907765 @default.
• W4240549069 cites W2149538353 @default.
• W4240549069 cites W2150844649 @default.
• W4240549069 cites W2153285335 @default.
• W4240549069 cites W2153865531 @default.
• W4240549069 cites W2156279531 @default.
• W4240549069 cites W2158350526 @default.
• W4240549069 cites W2159797831 @default.
• W4240549069 cites W2164688489 @default.
• W4240549069 cites W2170420697 @default.
• W4240549069 cites W2171521394 @default.
• W4240549069 cites W2314303973 @default.
• W4240549069 cites W2317722602 @default.
• W4240549069 cites W2318504037 @default.
• W4240549069 cites W2321449521 @default.
• W4240549069 cites W2323536234 @default.
• W4240549069 cites W2325419881 @default.
• W4240549069 cites W2328959105 @default.
• W4240549069 cites W2335535005 @default.
• W4240549069 cites W2335545834 @default.
• W4240549069 cites W2949918310 @default.
• W4240549069 cites W3004644874 @default.
• W4240549069 cites W30608356 @default.
• W4240549069 cites W4206899118 @default.
• W4240549069 cites W4233247338 @default.
• W4240549069 cites W4234113324 @default.
• W4240549069 cites W4240534210 @default.
• W4240549069 cites W4247742721 @default.
• W4240549069 cites W4249070114 @default.
• W4240549069 cites W4253244666 @default.
• W4240549069 cites W4255161658 @default.
• W4240549069 cites W4361807336 @default.
• W4240549069 cites W50595627 @default.
• W4240549069 doi "https://doi.org/10.1002/ange.201504494" @default.
• W4240549069 hasPublicationYear "2015" @default.
• W4240549069 type Work @default.
• W4240549069 citedByCount "30" @default.
• W4240549069 countsByYear W42405490692015 @default.
• W4240549069 countsByYear W42405490692016 @default.
• W4240549069 countsByYear W42405490692017 @default.
• W4240549069 countsByYear W42405490692018 @default.
• W4240549069 countsByYear W42405490692019 @default.
• W4240549069 countsByYear W42405490692020 @default.
• W4240549069 countsByYear W42405490692021 @default.

• next