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- W4240711270 abstract "Leucosceptroids A and B are sesterterpenoids with potent antifeedant and antifungal activities. A more efficient gram-scale total synthesis of leucosceptroid B and the first total synthesis of leucosceptroid A are presented. The key transformations include an aldol reaction between a substituted dihydrofuranone and an (S)-citronellal-derived aldehyde, a SmI2-mediated intramolecular ketyl–olefin radical cyclization, and final-stage alcohol oxidation." @default.
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- W4240711270 date "2014-12-03" @default.
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- W4240711270 title "Total Synthesis of Leucosceptroids A and B" @default.
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- W4240711270 doi "https://doi.org/10.1002/ange.201410134" @default.
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