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- W4240754152 abstract "Die Reaktion von Enin 1 mit [LAuCl] und AgSbF6 im Verhältnis 1:1 in CD2Cl2 bei −20 °C ergab den Gold-Komplex 2 in 97 % Ausbeute (NMR-Spektroskopie). Erwärmen von 2 in Lösung auf 25 °C führte über eine 1,3-H-Migration (t1/2≈16 min) mit 96 % Selektivität zum Gold-Komplex 3. 13C-NMR-Analysen von 2 und 3 zeigen einen überwiegenden Metallacyclopropan-Charakter der Gold-Bicyclo[3.2.0]hepten-Bindungen." @default.
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- W4240754152 date "2013-04-25" @default.
- W4240754152 modified "2023-09-24" @default.
- W4240754152 title "Direct Observation of a Cationic Gold(I)-Bicyclo[3.2.0]hept-1(7)-ene Complex Generated in the Cycloisomerization of a 7-Phenyl-1,6-enyne" @default.
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- W4240754152 doi "https://doi.org/10.1002/ange.201301640" @default.
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