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- W4240774348 abstract "The electrode reaction of the Mn(II)/Mn(Hg) system in acetonitrile and its mixtures with water has been studied. Charge-transfer rate constants, diffusion coefficients and formal potentials were determined. The transfer energies of Mn(II) from water to water+acetonitrile mixtures were calculated, based on potentials expressed in the ferrocene electrode scale. The charge transfer between Mn(I) and Mn(Hg) was found to control the rate of the electrode process in the whole composition range. The rate constants of this process go through a flat minimum as the concentration of acetonitrile increases. The change of the kinetics was explained using a slight modification of Behr's model." @default.
- W4240774348 created "2022-05-12" @default.
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- W4240774348 date "1983-03-10" @default.
- W4240774348 modified "2023-09-25" @default.
- W4240774348 title "The Mn(II)/Mn(Hg) electrode reaction in acetonitrile and its mixtures with water" @default.
- W4240774348 doi "https://doi.org/10.1016/0368-1874(83)80091-4" @default.
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