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- W4240806398 abstract "The creation of polystyrene latex particles through the nucleation of comparably sized styrene monomer droplets was investigated through experiment and mathematical modelling. Important preparative variables controlling the formation and stability of miniemulsion droplets were studied to reconcile disparate information gained in prior works. Conditions for the preparation of the smallest and most uniform droplets were optimized through inference from the subsequent polymerization kinetics and final particle size distributions. The effect of the presence of cetyl alcohol on the entry (and exit) of radicals was studied through seeded experiments in an attempt to explain the relatively slow nucleation observed in the polymerization of the systems prepared with this co-surfactant. A previously developed mathematical model was extended to include the thermodynamics describing the partition of components between the phases during the course of the polymerization." @default.
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- W4240806398 date "1992-06-03" @default.
- W4240806398 modified "2023-10-14" @default.
- W4240806398 title "Miniemulsion Polymerization" @default.
- W4240806398 doi "https://doi.org/10.1021/bk-1992-0492.ch006" @default.
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