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- W4240959903 abstract "Abstract A soluble and stable core‐modified [38]octaphyrin, MC‐T8 , containing eight thiophene rings was synthesized by Yamamoto coupling followed by oxidative dehydrogenation. X‐ray crystallographic analysis revealed a nearly planar backbone, and the molecule is globally aromatic with a dominant 38π conjugation pathway. The dication MC‐T8 2+ is antiaromatic, and the backbone is distorted, with a different orientation of the thiophene rings. The tetracation MC‐T8 4+ becomes aromatic again, with a shallow‐bowl‐shaped geometry. Both the neutral compound and the dication demonstrated open‐shell diradical character with a small singlet–triplet energy gap (−2.70 kcal mol −1 for MC‐T8 and −3.78 kcal mol −1 for MC‐T8 2+ ), and they are stable owing to effective spin delocalization." @default.
- W4240959903 created "2022-05-12" @default.
- W4240959903 creator A5012283082 @default.
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- W4240959903 date "2020-03-10" @default.
- W4240959903 modified "2023-10-16" @default.
- W4240959903 title "A Stable All‐Thiophene‐Based Core‐Modified [38]Octaphyrin Diradicaloid: Conformation and Aromaticity Switch at Different Oxidation States" @default.
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- W4240959903 doi "https://doi.org/10.1002/ange.202000188" @default.
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