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- W4240981393 abstract "Abstract N‐Alkynylindoles were divergently cyclized for the synthesis of multifused N‐heterocycles. An ortho ‐aryl palladium species was added to the α position of an ynamine to generate ( Z )‐6‐alkylidene/benzylidene‐6 H ‐isoindolo[2,1‐ a ]indoles, while Pt‐catalyzed β‐addition through π‐activation gave 5‐alkyl/arylindolo[2,1‐ a ]isoquinolines. Double cyclizations using PdCl 2 and oxidant afforded bright yellow benzo[7,8]indolizino[2,3,4,5‐ ija ]quinolines, the synthesis of which was also demonstrated in a different synthetic route." @default.
- W4240981393 created "2022-05-12" @default.
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- W4240981393 date "2017-09-18" @default.
- W4240981393 modified "2023-10-18" @default.
- W4240981393 title "Divergent C-H Annulation for Multifused N-Heterocycles: Regio- and Stereospecific Cyclizations of N-Alkynylindoles" @default.
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- W4240981393 doi "https://doi.org/10.1002/ange.201705514" @default.
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