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- W4241022079 abstract "During this quarter, we continued to study the X-ray absorption spectra of copper compounds. Here we report measurements of the high resolution XANES and EXAFS spectra at the sulfur K-edge (E=2472 eV). Using these results together with the information from other investigations, we attempted to gain a better understanding of the complicated chemical adsorption process taking place on the CuO/Al[sub 2]O[sub 3] surface. In the modeling work we have made a major modification of our methodology that will enable us to treat the adsorption of the SO[sub 2] molecule on the CuO/Al[sub 2]O[sub 3] surface. This involves adoption of a hybrid technique in which we use our previously developed two-dimensional periodic FLMTO technique to model a clean surface, and then use a molecular cluster model to represent the local environment giving changes with the SO[sub 2] adsorption. Experimental Work: The XANES and EXAFS measurements at the sulfur K-edge were carried out on beamline X-19A of the National Synchrotron Light Source (NSLS)." @default.
- W4241022079 created "2022-05-12" @default.
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- W4241022079 date "1989-01-01" @default.
- W4241022079 modified "2023-10-06" @default.
- W4241022079 title "[Surface studies of absorbents for the removal of SO[sub x] and NO[sub x]]" @default.
- W4241022079 doi "https://doi.org/10.2172/6809983" @default.
- W4241022079 hasPublicationYear "1989" @default.
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