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- W4241270812 abstract "A new series of highly conducting, one-dimensional (1-D) organic complexes based on the replacement of N-methylphenazinium (NMP+) with neutral phenazine (Phen) in (NMP+)(TCNQ-) (TCNQ- = 7,7,8,8-tetracyano-p-quinodimethane) is reported. The series of complexes was characterized by solution absorption spectra. X-ray diffraction, and differential scanning calorimetry (DCS). Up to 50% replacement of NMP+ with phenazine has been achieved. Thus an isomorphous series of highly conducting organic complexes permitting the study of the physical properties of 1-D substances as a controlled function of band filling (Fermi energy) and disorder has been realized. Conductivity results show a semiconducting behavior, with charge carriers activated to extended states with a large, strongly temperature dependent mobility. The energy gap is found to decrease with decreasing band filling, varying as the square. The inconsistency of these results with various disorder models is also indicated." @default.
- W4241270812 created "2022-05-12" @default.
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- W4241270812 date "1980-06-01" @default.
- W4241270812 modified "2023-09-27" @default.
- W4241270812 title "Mixed Phenazine-N-Methylphenazinium-7,7,8,8-Tetracyano-p-Quinodimethanide: A Quasi-One-Dimensional Metallike System with Variable Band Filling" @default.
- W4241270812 doi "https://doi.org/10.1021/ba-1970-0186.ch011" @default.
- W4241270812 hasPublicationYear "1980" @default.
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