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• W4241361514 abstract "Abstract The infrared spectra of ammonium, potassium, rubidium and cesium uranyl trinitrates (NH4UO2(NO3)3, KUO2(NO3)3, RbUO2(NO3)3 and CsUO2(NO3)3) have been measured in the region from 4000 cm−1 down to 30 cm−1. A normal coordinate analysis of the complexes has been made as a six-body problem (UO2 X3) (X=NO3) neglecting the outer cations. Force constants of U-O and U-X bonds in UO2X3 anion have been approximately obtained on the basis of a modified valence force field including an additional force constant of opposite U[sbnd]O bond-bond interaction. In addition, bond order of the uranyl bonds of the complexes has been determined from the U[sbnd]O stretching force constants and compared with those of other uranium compounds such as metal uranates and uranium oxides." @default.
• W4241361514 created "2022-05-12" @default.
• W4241361514 creator A5000295522 @default.
• W4241361514 date "1976-12-01" @default.
• W4241361514 modified "2023-09-24" @default.
• W4241361514 title "INFRARED SPECTROSCOPIC STUDIES OF SOME URANYL NITRATE COMPLEXES" @default.
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• W4241361514 doi "https://doi.org/10.1080/00958977608079889" @default.
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