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- W4241373453 abstract "Acr+–Mes acts as an efficient photoredox catalyst for the cis–trans isomerization of stilbene via the radical cation. The scope of the use of Acr+–Mes as an efficient electron-transfer photocatalyst for oxidation of organic compounds with O2 has been shown by examining photocatalytic oxygenation of toluene and cyclohexane with O2 and hydrochloric acid. These reactions are initiated by the electron transfer oxidation of Cl- with electron-transfer state of Acr+–Mes to form Cl, which cleaves the C–H bond of the substrates. Acr+–Mes was reported to act as an efficient organic photocatalyst for the oxidative bromination of aromatic hydrocarbons by O2 with hydrogen bromide to produce the monobrominated products selectively. Nicewicz and coworker utilized the high oxidizing ability of the electron transfer state of Acr+–Mes for the anti-Markovnikov hydroetherification of alkenols with 2-phenylmalononitrile as a redox-cycling source of a hydrogen atom, with complete regioselectivity without any trace of the undesired Markovnikov regioisomer." @default.
- W4241373453 created "2022-05-12" @default.
- W4241373453 date "2020-02-21" @default.
- W4241373453 modified "2023-10-18" @default.
- W4241373453 title "Photoredox Catalysis" @default.
- W4241373453 doi "https://doi.org/10.1002/9783527651771.ch7" @default.
- W4241373453 hasPublicationYear "2020" @default.
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