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- W4241488306 abstract "Abstract Ansellane‐type sesterterpenoids including, ansellones A‐G and (+)‐phorbadione are structurally novel marine secondary metabolites which exhibit anticancer and anti‐HIV activity. The first, asymmetric total syntheses of three structurally representative members, (−)‐ansellones A and B and (+)‐phorbadione, were accomplished in 16–23 steps from (+)‐sclareolide. The route features the first regioselective cyclization of vinyl epoxides with internal alcohol nucleophiles in a 1,4‐addition manner (S N 2′). Additionally, the allylic C−H oxidation was exploited at a late stage of the synthesis of (−)‐ansellone A and (+)‐phorbadione. This strategy is expected to be applicable to the synthesis of other ansellane sesterterpenoids." @default.
- W4241488306 created "2022-05-12" @default.
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- W4241488306 date "2017-03-28" @default.
- W4241488306 modified "2023-10-15" @default.
- W4241488306 title "Total Syntheses of Sesterterpenoid Ansellones A and B, and Phorbadione" @default.
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- W4241488306 doi "https://doi.org/10.1002/ange.201701879" @default.
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