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- W4241585139 abstract "Wählerisch: Chirale tetraedrische Käfige entstehen durch diastereoselektive Selbstorganisation enantiomerenreiner C2-symmetrischer Biphenylbis(β-diketonat)-Liganden und C3-symmetrischer, oktaedrisch koordinierter Fe3+- oder Ga3+-Ionen (siehe Bild; Fe violett, C blau, O rot; Hohlraum als orangefarbene Kugel). Die hohlen Polyeder zeigen ein metallabhängiges chiroptisches Verhalten und wirken als Wirt bei der Trennung racemischer Alkohole durch Kristallisation (bis 99.5 % ee). Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W4241585139 date "2010-05-10" @default.
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- W4241585139 title "Chiral Nanoscale Metal-Organic Tetrahedral Cages: Diastereoselective Self-Assembly and Enantioselective Separation" @default.
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- W4241585139 doi "https://doi.org/10.1002/ange.201000416" @default.
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