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- W4241626105 abstract "Abstract The first Au III carbene complex was prepared by reacting a geminal dianion with a (P,C) cyclometalated Au III precursor. Its structure and bonding situation have been thoroughly investigated by experimental and computational means. The presence of a high‐energy highest occupied molecular orbital (HOMO) centered at the carbene center suggests nucleophilic character for the Au III carbene complex. This unprecedented feature was confirmed by reactions with two electrophiles (PhNCS and CS 2 ), resulting in two types of C=C coupling reactions." @default.
- W4241626105 created "2022-05-12" @default.
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- W4241626105 date "2017-08-24" @default.
- W4241626105 modified "2023-10-01" @default.
- W4241626105 title "A Nucleophilic Gold(III) Carbene Complex" @default.
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- W4241626105 doi "https://doi.org/10.1002/ange.201706197" @default.
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