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- W4241660419 abstract "Eine ungewöhnliche C-C-Kupplung durch konjugierte radikalische Addition führt mit hoher Enantioselektivität zum Produkt der Aldol-artigen Reaktion (siehe Schema). Anders als bei der ionischen Variante verläuft die radikalische enantioselektive nucleophile Addition an β-Acyloxyenoate ohne Eliminierung. Der entscheidene Schritt ist die radikalische Si-Addition an ein s-cis-Konformer des Substrats." @default.
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- W4241660419 date "2003-09-25" @default.
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- W4241660419 title "Enantioselective Conjugate Radical Addition toβ-Acyloxy Acrylate Acceptors: An Approach to Acetate Aldol-Type Products" @default.
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- W4241660419 doi "https://doi.org/10.1002/ange.200352096" @default.
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