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- W4241796628 abstract "<p>Palladium catalysed hydrogenolysis is often the final step in challenging natural product total synthesis and a key step in industrial processes towards fine chemicals. Here we demonstrate that there is wide variability in quality of commercial sources of palladium on carbon (Pd/C), which results in differences in selectivity, reaction times, and yields. This is established through a combination of XRD, XPS, BET and TEM analysis, this will serve as a template for others to quickly identify a high-quality source of Pd/C catalyst — meaning less time spent on time consuming reaction optimisation studies. Key indicators of a high-quality catalyst include: small particle sizes, large surface area, and the presence of both Pd<sup>0</sup> and Pd<sup>2+ </sup>active species (not present in all commercial sources). Further this work will enable the design and synthesis of new high-quality Pd/C catalysts.</p>" @default.
- W4241796628 created "2022-05-12" @default.
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- W4241796628 date "2020-12-23" @default.
- W4241796628 modified "2023-09-28" @default.
- W4241796628 title "Variation in the Structure and Activity of Commercial Palladium on Carbon Catalysts" @default.
- W4241796628 doi "https://doi.org/10.26434/chemrxiv.12793634.v2" @default.
- W4241796628 hasPublicationYear "2020" @default.
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