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- W4241844451 abstract "Abstract We present an expedient and economical route to a new spiroketal‐based C 2 ‐symmetric chiral scaffold, termed SPIROL. Based on this spirocyclic scaffold, several chiral ligands were generated. These ligands were successfully employed in an array of stereoselective transformations, including in iridium‐catalyzed hydroarylations (up to 95 % ee ), palladium‐catalyzed allylic alkylations (up to 97 % ee ), intermolecular palladium‐catalyzed Heck couplings (up to 94 % ee ), and rhodium‐catalyzed dehydroalanine hydrogenation (up to 93 % ee )." @default.
- W4241844451 created "2022-05-12" @default.
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- W4241844451 date "2018-03-23" @default.
- W4241844451 modified "2023-09-26" @default.
- W4241844451 title "Design, Synthesis, and Application of Chiral <i>C</i> <sub>2</sub> ‐Symmetric Spiroketal‐Containing Ligands in Transition‐Metal Catalysis" @default.
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- W4241844451 doi "https://doi.org/10.1002/ange.201713304" @default.
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