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- W4241869732 abstract "The highly reversible zinc-bromine redox couple has been successfully applied in the zinc-bromine flow batteries; however, non-electroactive pump/pipe/reservoir parts and ion-selective membranes are essential to suppress the bromine diffusion. This work demonstrates a zinc-bromine static (non-flow) battery without these auxiliary parts and utilizing glass fiber separator, which overcomes the high self-discharge rate and low energy efficiency while the advantages of the zinc-bromine chemistry are well preserved. It is achieved by a multifunctional additive, tetrapropylammonium bromide (TPABr), which not only mitigates the bromine cross-diffusion by regulating the fluidic bromine to a condensed solid phase but also provides a favorable interface for zinc electrodeposition toward non-dendritic growth. The proposed zinc-bromine static battery demonstrates a high specific energy of 142 Wh kg−1 with a high energy efficiency up to 94%. By optimizing the porous electrode architecture, the battery shows an ultra-stable cycling life for over 11,000 cycles with controlled self-discharge rate." @default.
- W4241869732 created "2022-05-12" @default.
- W4241869732 date "1913-10-01" @default.
- W4241869732 modified "2023-10-14" @default.
- W4241869732 title "Purification and concentration of radium barium chlorides" @default.
- W4241869732 doi "https://doi.org/10.1016/s0016-0032(13)90380-x" @default.
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