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- W4241873397 abstract "Selective tuning of arylethynyl urea scaffolds for anionic guests requires an understanding of preferred binding motifs of the host-guest interaction. To investigate the binding preference of receptors without a pre-organized binding pocket, two electron-deficient phenylacetylene receptors with a single urea moiety have been prepared and were found to bind halides as 2:1 host-guest complexes that feature key CH-anion or anion-π interactions. These supporting interactions also appear to influence the mechanism of the 2:1 binding event." @default.
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- W4241873397 date "2017-03-06" @default.
- W4241873397 modified "2023-09-27" @default.
- W4241873397 title "Do CH-Anion and Anion-π Interactions Alter the Mechanism of 2:1 Host-Guest Complexation in Arylethynyl Monourea Anion Receptors?" @default.
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- W4241873397 doi "https://doi.org/10.1002/chem.201605452" @default.
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