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- W4242073029 abstract "The adsorption and enthalpy of displacement in methanol—benzene mixtures have been studied on adsorbents with different surface polarities: hydrophobic silica, activated carbon and graphitized carbon black. An investigation of systems producing S-shaped excess isotherms was conducted to determine which function transformations can be used to transform the integral enthalpy of displacement isotherms into the function ψs1 = f (ø1), the shape of which corresponds to the function øs1 = f (ø1) calculated from the excess isotherms. It has been established that, in the event of ideal behaviour of the adsorption layer (ΔHse = 0), the composition of the interfacial layer (ø s1) is identical to the displacement factor (ψs1), i.e. the composition of the surface layer can be determined merely from calorimetric data. The excess enthalpy of the adsorption layer (ΔHse≠ 0) on the surface of the graphitized carbon black adsorbent with a homogeneous surface energy distribution agrees to a good approximation with that of the bulk phase measured experimentally." @default.
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- W4242073029 date "1987-03-01" @default.
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- W4242073029 title "Enthalpy of displacement of binary liquid mixtures on solid surfaces part II. Analysis of S-shaped excess isotherms" @default.
- W4242073029 doi "https://doi.org/10.1016/0166-6622(87)80248-2" @default.
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