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- W4242271853 endingPage "2104" @default.
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- W4242271853 abstract "Abstract Transition‐metal‐mediated metalation of an aromatic C−H bond that is adjacent to a tertiary phosphine group in arylphosphines via a four‐membered chelate ring was first discovered in 1968. Herein, we overcome a long‐standing problem with the ortho ‐C−H activation of arylphosphines in a catalytic fashion. In particular, we developed a rhodium‐catalyzed ortho ‐selective C−H borylation of various commercially available arylphosphines with B 2 pin 2 through P III ‐chelation‐assisted C−H activation. This discovery is suggestive of a generic platform that could enable the late‐stage modification of readily accessible arylphosphines." @default.
- W4242271853 created "2022-05-12" @default.
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- W4242271853 date "2019-01-25" @default.
- W4242271853 modified "2023-10-09" @default.
- W4242271853 title "Rhodium-Catalyzed P<sup>III</sup> -Directed <i>ortho</i> -C−H Borylation of Arylphosphines" @default.
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- W4242271853 doi "https://doi.org/10.1002/ange.201813452" @default.
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