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- W4242326677 abstract "Abstract The symmetry breaking of meso primary diols bearing a tetrahydropyran ring was employed, using catalytic asymmetric acyl transfer, to control all‐carbon quaternary stereocenters. The planar chiral Fu DMAP catalyst was used in this reaction to reach a high degree of enantioselectivity (up to 97:3 e.r.) through a synergic effect combining a desymmetrization step and a kinetic resolution. Moreover, a beneficial effect was exhibited by C 6 F 6 solvent, yielding the first example of an organocatalyzed asymmetric acyl transfer. The desymmetrized monoesters were then used to obtain, after a straightforward ring opening sequence, complex polyketide building blocks bearing all‐carbon quaternary stereocenters." @default.
- W4242326677 created "2022-05-12" @default.
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- W4242326677 date "2013-12-06" @default.
- W4242326677 modified "2023-10-18" @default.
- W4242326677 title "Stereocontrol of All-Carbon Quaternary Centers through Enantioselective Desymmetrization of<i>Meso</i>Primary Diols by Organocatalyzed Acyl Transfer" @default.
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- W4242326677 doi "https://doi.org/10.1002/ange.201308268" @default.
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