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- W4242370879 abstract "[661-69-8] C6H18Sn2 (MW 327.66) InChI = 1S/6CH3.2Sn/h6*1H3;; InChIKey = CCRMAATUKBYMPA-UHFFFAOYSA-N (palladium-catalyzed substitution and addition reactions) Physical Data: colorless oil, bp 62–63 °C/12 mmHg, 182 °C/756 mmHg; mp 23 °C; nD20 = 1.5321. Solubility: sol most organic solvents. Form Supplied in: colorless oil; readily available but highly expensive. Analysis of Reagent Purity: 119Sn NMR recommended (δ −109 ppm, 1J(119Sn–119Sn) 4404 Hz).8 Preparative Methods: although the preparation from Trimethylstannane and trimethyl(diethylamino)stannane affords an excellent yield (95%), it has the disadvantage of requiring two extremely air-sensitive starting materials.2 Better methods involve the use of Chlorotrimethylstannane with either Lithium or Sodium,3 or Trimethylstannyllithium (the latter from trimethylstannane and Lithium Diisopropylamide4).5 Catalytic elimination of hydrogen from trimethylstannane also affords hexamethyldistannane and can be effected either by various bases6a or by palladium catalysts such as Tetrakis(triphenylphosphine)palladium(0).6b This latter method can be recommended. The preparation of hexamethyldistannane starting from bis(trimethylstannyl) sulfide has also been described.7 Handling, Storage, and Precautions: the compound must be stored in the absence of oxygen, moisture, and light (preferably under argon). Very highly toxic. Use in a fume hood." @default.
- W4242370879 created "2022-05-12" @default.
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- W4242370879 date "2010-10-15" @default.
- W4242370879 modified "2023-09-30" @default.
- W4242370879 title "Hexamethyldistannane" @default.
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- W4242370879 doi "https://doi.org/10.1002/047084289x.rh018.pub2" @default.
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