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- W4242402536 abstract "O2 rein, H2O raus: Verschiedene Diamine und verwandte Bisnucleophile reagieren in einer oxidativen Insertion von Isocyanid mit Pd(OAc)2 (1 Mol-%) als Katalysator und O2 als eigentlichem Oxidans zu einer Reihe medizinisch relevanter N-Heterocyclen. Der Nutzen dieser nachhaltigen Methode wird anhand der formalen Synthese der Antihistamine Astemizol und Norastemizol demonstriert." @default.
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- W4242402536 date "2012-11-14" @default.
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- W4242402536 title "Sustainable Synthesis of Diverse Privileged Heterocycles by Palladium-Catalyzed Aerobic Oxidative Isocyanide Insertion" @default.
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- W4242402536 doi "https://doi.org/10.1002/ange.201207410" @default.
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