Matches in SemOpenAlex for { <https://semopenalex.org/work/W4242420909> ?p ?o ?g. }
Showing items 1 to 60 of
60
with 100 items per page.
- W4242420909 endingPage "483" @default.
- W4242420909 startingPage "482" @default.
- W4242420909 abstract "Recent measurements of the catalytic activity of a series of transition metal sulfides showed that the ability of a particular sulfide to catalyze the HDS reaction is related to the position of the transition metal in the periodic table (Pecoraro, T. A., and Chianelli, R. R., J. Catal.67, 430 (1981)). In order to understand the specific origin of these periodic trends in activity, SCF-Xα calculations of the electronic structure of cluster models of the first and second row transition metal sulfides were carried out. The results of these calculations were used to identify several electronic factors which appear to be related to the catalytic activity of the transition metal sulfides. The computed quantities which measure these factors were combined to form an activity parameter for each sulfide. This parameter shows a direct correlation with the catalytic activity of the sulfides. A model for the binding of thiophenic molecules to the surface of the sulfide catalyst is suggested. This model is consistent both with the correlation between bulk electronic structure and catalytic activity of the sulfides and with the ligand properties of thiophene in transition metal complexes." @default.
- W4242420909 created "2022-05-12" @default.
- W4242420909 date "1982-12-01" @default.
- W4242420909 modified "2023-09-30" @default.
- W4242420909 title "Author index for volume 78" @default.
- W4242420909 doi "https://doi.org/10.1016/0021-9517(82)90334-7" @default.
- W4242420909 hasPublicationYear "1982" @default.
- W4242420909 type Work @default.
- W4242420909 citedByCount "0" @default.
- W4242420909 crossrefType "journal-article" @default.
- W4242420909 hasConcept C106773901 @default.
- W4242420909 hasConcept C147597530 @default.
- W4242420909 hasConcept C147789679 @default.
- W4242420909 hasConcept C161790260 @default.
- W4242420909 hasConcept C164866538 @default.
- W4242420909 hasConcept C178790620 @default.
- W4242420909 hasConcept C179104552 @default.
- W4242420909 hasConcept C185592680 @default.
- W4242420909 hasConcept C197129369 @default.
- W4242420909 hasConcept C199360897 @default.
- W4242420909 hasConcept C2779953032 @default.
- W4242420909 hasConcept C2780596425 @default.
- W4242420909 hasConcept C32909587 @default.
- W4242420909 hasConcept C41008148 @default.
- W4242420909 hasConcept C544153396 @default.
- W4242420909 hasConceptScore W4242420909C106773901 @default.
- W4242420909 hasConceptScore W4242420909C147597530 @default.
- W4242420909 hasConceptScore W4242420909C147789679 @default.
- W4242420909 hasConceptScore W4242420909C161790260 @default.
- W4242420909 hasConceptScore W4242420909C164866538 @default.
- W4242420909 hasConceptScore W4242420909C178790620 @default.
- W4242420909 hasConceptScore W4242420909C179104552 @default.
- W4242420909 hasConceptScore W4242420909C185592680 @default.
- W4242420909 hasConceptScore W4242420909C197129369 @default.
- W4242420909 hasConceptScore W4242420909C199360897 @default.
- W4242420909 hasConceptScore W4242420909C2779953032 @default.
- W4242420909 hasConceptScore W4242420909C2780596425 @default.
- W4242420909 hasConceptScore W4242420909C32909587 @default.
- W4242420909 hasConceptScore W4242420909C41008148 @default.
- W4242420909 hasConceptScore W4242420909C544153396 @default.
- W4242420909 hasIssue "2" @default.
- W4242420909 hasLocation W42424209091 @default.
- W4242420909 hasOpenAccess W4242420909 @default.
- W4242420909 hasPrimaryLocation W42424209091 @default.
- W4242420909 hasRelatedWork W1972956966 @default.
- W4242420909 hasRelatedWork W1994587093 @default.
- W4242420909 hasRelatedWork W2016734730 @default.
- W4242420909 hasRelatedWork W2026353549 @default.
- W4242420909 hasRelatedWork W2038682917 @default.
- W4242420909 hasRelatedWork W2090972994 @default.
- W4242420909 hasRelatedWork W2552038845 @default.
- W4242420909 hasRelatedWork W282366058 @default.
- W4242420909 hasRelatedWork W818553673 @default.
- W4242420909 hasRelatedWork W2503493866 @default.
- W4242420909 hasVolume "78" @default.
- W4242420909 isParatext "false" @default.
- W4242420909 isRetracted "false" @default.
- W4242420909 workType "article" @default.