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- W4242455819 abstract "On the basis of the study of the solvent, temperature, and pressure effects, we show how the NMR rotational correlation times ξ2R for a heavy water molecule in neat liquid and organic solvents are correlated with the strength of solute-solvent interactions, in particular, H bonds. At room temperature (30 °C), the correlation time is 2.1 ps in the random H-bond network in heavy water, whereas it is as small as 0.1 ps in such an apolar, hydrophobic solvent as carbon tetrachloride because of the absence of the H bonds between water molecules. Pressure distorts H bonds and accelerates the orientational motion of water molecules in neat liquid. Firm evidence is collected for the limitations of the Stokes-Einstein-Debye (SED) law in solution." @default.
- W4242455819 created "2022-05-12" @default.
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- W4242455819 date "1995-01-01" @default.
- W4242455819 modified "2023-09-27" @default.
- W4242455819 title "Effect of solvent, temperature, and pressure on hydrogen bonding and reorientation of water molecules" @default.
- W4242455819 doi "https://doi.org/10.1016/s0167-6881(06)80772-x" @default.
- W4242455819 hasPublicationYear "1995" @default.
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