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• W4242681623 abstract "The catalytic asymmetric Diels–Alder reaction of quinone imine ketals with diene carbamates catalyzed by axially chiral dicarboxylic acids is reported herein. A variety of primary and secondary alkyl-substituted quinone derivatives which have not been applied in previous asymmetric quinone Diels–Alder reactions could be employed using this method. More importantly, we succeeded in developing a strategy to divert the reaction site in unsymmetrical 3-alkyl quinone imine ketals from the inherently favored unsubstituted CC bond to the disfavored alkyl-substituted CC bond." @default.
• W4242681623 created "2022-05-12" @default.
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• W4242681623 date "2015-02-16" @default.
• W4242681623 modified "2023-10-07" @default.
• W4242681623 title "Catalytic Asymmetric Diels-Alder Reaction of Quinone Imine Ketals: A Site-Divergent Approach" @default.
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• W4242681623 doi "https://doi.org/10.1002/ange.201410957" @default.
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