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- W4242756976 abstract "An original step-by-step approach to synthesize and characterize a bifunctional heterogeneous catalyst consisting of isolated Ti3+ centers and strong Lewis acid Al3+ sites on the surface of a chlorinated alumina has been devised. A wide range of physicochemical and spectroscopic techniques were employed to demonstrate that the two sites, in close proximity, act in a concerted fashion to synergistically boost the conversion of ethylene into branched polyethylene, using ethylene as the only feed and without any activator. The coordinatively unsaturated Al3+ ions promote ethylene oligomerization through a carbocationic mechanism and activate the Ti3+ sites for the traditional ethylene coordination polymerization." @default.
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- W4242756976 date "2016-07-21" @default.
- W4242756976 modified "2023-10-18" @default.
- W4242756976 title "Unraveling the Catalytic Synergy between Ti<sup>3+</sup>and Al<sup>3+</sup>Sites on a Chlorinated Al<sub>2</sub>O<sub>3</sub>: A Tandem Approach to Branched Polyethylene" @default.
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- W4242756976 doi "https://doi.org/10.1002/ange.201604136" @default.
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