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- W4242832014 abstract "This chapter contains a comprehensive compilation of the available experimental and theoretical vibrational data for alkyl, alkylidyne, and alkylidene complexes. It discusses the importance of this information and its role in evaluating structures, bonding, and other important properties. The chapter also treats the use of discrete Fourier transform (DFT) and other theoretical calculations to analyze the vibrational data and to predict properties associated with these compounds. It then includes vibrational data for organic species that are formed on various surfaces. Raman band shape analysis of the symmetric Si-ligand stretching modes was used to determine vibrational correlation functions and related spectral data for liquid (CH3)3SiCl. Vibrational data for alkyl-metal halides are discussed separately for each group of the periodic table. Early cryoscopic measurements showed that dialkylaluminum hydrides are trimers for both the pure liquids and solutions." @default.
- W4242832014 created "2022-05-12" @default.
- W4242832014 date "2018-11-28" @default.
- W4242832014 modified "2023-10-17" @default.
- W4242832014 title "Alkyl, Alkylidyne, and Alkylidene Complexes with Other Functional Groups" @default.
- W4242832014 doi "https://doi.org/10.1002/9781119404675.ch13" @default.
- W4242832014 hasPublicationYear "2018" @default.
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