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- W4242834513 abstract "A highly efficient catalyst system based on ruthenium-pincer-type complexes has been discovered for N-formylation of various amines with CO2 and H2, thus affording the corresponding formamides with excellent productivity (turnover numbers of up to 1 940 000 in a single batch) and selectivity. Using a simple catalyst recycling protocol, the catalyst was reused for 12 runs in N,N-dimethylformamide production without significant loss of activity, thus demonstrating the potential for practical utilization of this cost-effective process. A one-pot two-step procedure for hydrogenation of CO2 to methanol via the intermediacy of formamide formation has also been developed." @default.
- W4242834513 created "2022-05-12" @default.
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- W4242834513 date "2015-04-07" @default.
- W4242834513 modified "2023-10-12" @default.
- W4242834513 title "Highly Efficient Ruthenium-Catalyzed N-Formylation of Amines with H<sub>2</sub>and CO<sub>2</sub>" @default.
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- W4242834513 doi "https://doi.org/10.1002/ange.201500939" @default.
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