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- W4242894417 abstract "Optical and optical Stark spectra of the 000 à 2E-X̃ 2A1 band system of a supersonic molecular beam sample of calcium monomethyl, CaCH3, have been recorded. Field free spectroscopic parameters were obtained on fitting the (|KR′|=1, |K′|=0 and 2)–(|KR″|=1) and the (|KR′|=0, |K′|=1)–(|KR″|=0) subbands. The branch features were reassigned and a resulting new set of spectroscopic parameters determined. The value of the a-principal axis component of the spin–rotation parameter, εaa(à 2E), is now consistent with the assumed nature of the low-lying excited electronic states. Dipole moments of 2.62±0.03 D and 1.69±0.02 D were determined for the X̃ 2A1 and à 2E states, respectively. A simple electrostatic model was adapted to predict dipole moments for CaCH3 and MgCH3." @default.
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- W4242894417 date "1996-09-08" @default.
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- W4242894417 title "A molecular beam optical/Stark study of calcium monomethyl" @default.
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- W4242894417 doi "https://doi.org/10.1063/1.472265" @default.
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